Bio-sorption of methylene blue using Datura stramonium leaves as adsorbent
Abstract
Present study was accomplished to prospect the viability of using the Datura stramonium leaves powder (DS) as an adsorbent to remove the methylene blue from aqueous solution. The physico-chemical characteristics of the studied adsorbent were examined. The optimum parameters such as contact time, particle size, absorbent dose, initial methylene blue concentration, and pH were investigated by performing batch experiments models. The kinetics and the isotherms adsorption were evaluated by varying the initial concentration and using the optimum parameters. The optimum of contact time is 30min, with a removal capacity of 89.60 %. The optimal adsorbent concentration to reach the maximum removal of methylene blue (89.54 %) is 18 g/L. An initial methylene blue concentration of 50 ppm is ideal to reach the maximum capacity of removal (92.72 %). The optimum particle size is 80 mm. The kinetics of the adsorption process are in accordance with the pseudo-second order model. Experimental values of the adsorption capacity are close proximity to the optimum values predicted by the pseudo-second order model. Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Harkin-Jura and Hasley isotherms were applied to represent the data obtained from the adsorption studies. The highest R2 values were related to Freundlich, Dubinin-Radushkevich and Hasley isotherm models.
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