Inhibition of aluminum corrosion in hydrochloric acid medium by 2-(2-(4chlorobenzylidene)hydrazinyl)-3-nitroimidazo[1,2-a]pyridine: gravimetric and adsorption studies
Abstract
The purpose of this study is to evaluate the corrosion-inhibiting efficacy of the 2-(2-(4-chlorobenzylidene)hydrazinyl)-3-nitroimidazo[1,2-α] pyridine, or 4Cl-BNH-NIP, on aluminum corrosion in a 1 M hydrochloric acid medium using the gravimetric method. The corrosion inhibition efficiency increases with inhibitor concentration but decreases with increasing temperature. Adsorption isotherm models (Langmuir, El-Awady, Freundlich, Flory-Huggins, Frunkin, and Temkin) were used to describe the interactions between the molecule and metallic aluminum. The Dubinin-Radushkevich and Adejo-Ekwenchi isotherms were used to identify the adsorption modes. The thermodynamic parameters of adsorption and activation were also determined and analyzed in this study.
Downloads
References
Davis, J. R. (Ed.). (1993). Aluminum and aluminum alloys. Materials Park, OH: ASM International, pp. 1–784.
Polmear, I. J. (2006). Light alloys: metallurgy of the light metals (4th ed.). Oxford, UK: Butterworth-Heinemann, pp. 1–421. https://doi.org/10.1016/B978-075066371-7/50005-0
Fontana, M. G. (2005). Corrosion engineering (3rd ed.). New York, NY: McGraw-Hill, pp. 1–556.
Revie, R. W., & Uhlig, H. H. (2008). Corrosion and corrosion control: an introduction to corrosion science and engineering (4th ed.). Hoboken, NJ: John Wiley & Sons, pp. 1–512. https://doi.org/10.1002/9780470277270
Landolt, D. (2007). Corrosion and surface chemistry of metals. Lausanne, Switzerland: EPFL Press, pp. 1–615. https://doi.org/10.1201/9781439807880
CETIM. (2021). Rapport sur les coûts de la corrosion. Senlis, France: Centre Technique des Industries Mécaniques, pp. 1–98.
Obot, I. B., Macdonald, D. D., & Gasem, Z. M. (2015). Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors. Corrosion Science, 99, 1–30. https://doi.org/10.1016/j.corsci.2015.01.037
Bentiss, F., Traisnel, M., & Lagrenée, M. (2000). The substituted 1,3,4-oxadiazoles: A new class of corrosion inhibitors of mild steel in acidic media. Corrosion Science, 42(1), 127–146. https://doi.org/10.1016/S0010-938X(99)00049-9
ASTM International. (2004). ASTM G31-72(2004): Standard practice for laboratory immersion corrosion testing of metals. West Conshohocken, PA: ASTM International, pp. 1–8.
Khadom, A. A., Yaro, A. S., & Kadhum, A. A. H. (2010). Corrosion inhibition by naphthylamine and phenylenediamine for the corrosion of copper-nickel alloy in hydrochloric acid. Journal of the Taiwan Institute of Chemical Engineers, 41(1), 122–125. https://doi.org/10.1016/j.jtice.2009.08.001
Musa, A. Y., Khadom, A. A., Kadhum, A. A. H., Mohamad, A. B., & Takriff, M. S. (2010). Kinetic behavior of mild steel corrosion inhibition by 4-amino-5-phenyl-4H-1,2,4-triazole-3-thiol. Journal of the Taiwan Institute of Chemical Engineers, 41(1), 126–128. https://doi.org/10.1016/j.jtice.2009.08.002
Rahim, A. A., & Kassim, J. (2008). Recent development of vegetal tannins in corrosion protection of iron and steel. Recent Patents on Materials Science, 1(3), 223–231. https://doi.org/10.2174/1874464810801030223
Touré, R. H., Koffi, A. A., Tigori, M. A., & Niamien, P. M. (2024). Investigation on the properties of methyl 4-(((1H-benzimidazol-2-yl)methyl)thio)methyl benzoate on aluminum corrosion in acidic environment. American Journal of Applied Chemistry, 12(6), 135–148. https://doi.org/10.11648/j.ajac.20241206.12
Yeo, M., Tigori, M. A., Kouyaté, A., Niamien, P. M., & Trokourey, A. (2020). Inhibition of aluminium corrosion in 1 M HCl by pyridoxine hydrochloride: Thermodynamic and quantum chemical studies. International Research Journal of Pure and Applied Chemistry, 21(21), 20–38. https://doi.org/10.9734/irjpac/2020/v21i2130286
N’Guessan, Y. S., Gbe, G. D., Lemeyonouin, A. G., Niamien, P. M., & Trokourey, A. (2018). Aluminum corrosion inhibition by 7-(ethylthiobenzimidazolyl) theophylline in 1 M hydrochloric acid: Experimental and DFT studies. International Journal of Applied Pharmaceutical Sciences and Research, 3(1), 41–53. https://doi.org/10.21477/ijapsr.3.4.1
Villamil, R. F. V., Corio, P., Rubin, J. C., & Agostinho, S. M. L. (1999). Effect of sodium dodecyl sulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole. Journal of Electroanalytical Chemistry, 472(1–2), 112–116. https://doi.org/10.1016/S0022-0728(99)00267-3
Fiala, A., & Mechehoud, Y. (2012). Étude de l’effet inhibiteur du 2-(1,3-dithiétan-2-ylidène)-3-oxobutanoate de méthyle et du 2-(1,3-dithiolane-2-ylidène)-3-oxobutanoate de méthyle sur la corrosion du cuivre en milieu nitrique 3 mol·L⁻¹. Sciences & Technologie, Section A, 35, 23–30.
Bockris, J. O’M., & Reddy, A. K. N. (1977). Modern electrochemistry. New York, NY: Plenum Press, pp. 1–834.
Gece, G. (2008). The use of quantum chemical methods in corrosion inhibitor studies. Corrosion Science, 50(11), 2981–2992. https://doi.org/10.1016/j.corsci.2008.08.043
Banerjee, G., & Malhotra, S. N. (1992). Contribution to the adsorption of corrosion inhibitors on metal surfaces. Corrosion Science, 32(10), 1051–1060. https://doi.org/10.5006/1.3315912
Touré, H. R., Bamba, A., Ehouman, A. D., & Niamien, P. M. (2024). Study of the inhibitory properties of 2-((benzylthio)methyl)-1H-benzo[d]imidazole with respect to the corrosion of aluminum in a nitric acid medium. Earthline Journal of Chemical Sciences, 11(3), 471–487. https://doi.org/10.34198/ejcs.11324.471487
Aphouet, A. K., N’Guadi, B. A., Mougo, A. T., Teminfolo, Y. S., Trokourey, A., & Niamien, P. M. (2023). Study of expired Fuclo 500 drug as an environmentally sustainable corrosion inhibitor. European Journal of Chemistry, 14(3), 353–361. https://doi.org/10.5155/eurjchem.14.3.353-361.2443
This work is licensed under a Creative Commons Attribution 4.0 International License.
